CHEM 646: Physical Chemistry I (4 credits)

Fall 1999

The course gives an introduction to the basic principles of thermodynamics, changes of state, properties of solutions, phase equilibria, chemical equilibriaand chemical reaction kinetics.

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Line number: 19268

Instructor: Krzysztof Kuczera, 5088 Malott, phone: 864-5060

kkuczera@ukans.edu

Time & Place: 8:00 - 9:20 MWF, 2001 Malott

Textbook: P. W. Atkins, Physical Chemistry, 6 tex2html_wrap_inline73 Ed.

Prerequisites: CHEM 188, PHSX 211 & 212, MATH 121 & 122

Discussion sections: We will hold discussions on Thursdays 3:30-5:20

Office hours: T,W 10:00-11:00 am or by appointment

The overall grade will be determined by the sum of three components: the homework, the average of the best two scores from the three partial exams (hour-exam) and the final exam score (final-exam):

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Exam dates:

 
                   		  Exam 1  		 September 17

Exam 2 October 22

Exam 3 November 19

FINAL Thursday, December 9, 7:30-10:30 am

Problem solving:

Learning physical chemistry involves mastering a number of complex concepts. This cannot be achieved without the experience and insight gained by problem solving. A number of sample problem solutions are given in the textbook. Further examples will be solved in class. Finally, each week a set of problems will be assigned to be solved at home; solutions will be given the following week. Solutions for the problem set will also be one of the topics covered in the discussion sections. Familiarity with the problems dealt with in the textbook, class and homework examples is absolutely necessary for success in the exams.

Reading:

It is recommended that the students read the relevant chapters of the textbook both before and after the material is covered in class.

Further reading:

In order to better understand the material it is useful to familiarize oneself with at least one additional text on the subject besides the course textbook. The following books contain good alternative presentations of the course material:

  General:

1. Alberty and Silbey, Physical Chemistry, 1 tex2html_wrap_inline75 or 2 tex2html_wrap_inline77 Ed.

2. Levine, Physical Chemistry, 4 tex2html_wrap_inline73 Ed.

  Biologically oriented:

3. Eisenberg and Crothers, Physical Chemistry with Applications to the Life Sciences.

  Highly theoretical:

4. Callen, Thermodynamics.


08/20-08/23 Introduction, Properties of Gases 0,1

08/25-09/15 The First Law of Thermodynamics 2,3

09/17 Exam #1

09/20-10/08 The Second Law of Thermodynamics 4,5

10/11-10/13 Phase Changes of Pure Substances 6

10/15-10/20 Thermodynamics of Mixtures 7

10/22 Exam #2

10/25-10/29 Phase Equilibria 8

11/01-11/12 Chemical Equilibrium 9

11/15-11/17 Transport Phenomena: Molecular Motions 24

11/19 Exam #3

11/22-12/06 Chemical Reactions: Rates & Dynamics 25,27

Class website:

Lecture notes, homework assignments and sample exam questions will be on the site

      http://oolung.chem.ukans.edu/~kuczera/646/646.html

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